Home > Published Issues > 2020 > Volume 9, No. 9, September 2020 >

Development of Sulfonic Supported Acids and Their Application in Power to Gas Systems

Rosanna Viscardi 1, Vincenzo Barbarossa 2, Raimondo Maggi 2, and Francesco Pancrazzi 2
1. ENEA, Casaccia Research Center, Santa Maria di Galeria, Roma, Italy
2. ENEA, Casaccia Research Center, Santa Maria di Galeria, Roma, Italy
University of Parma, Department of Chemical and Life Sciences and Environmental Sustainability, Parma, Italy

Abstract—Dimethyl ether (DME) is an environmentally friendly fuel that is being widely considered as an alternative fuel to replace petroleum fuels. DME can be produced by dehydration reaction of methanol by using solid catalysts in catalytic reactions. This study shows the influence of catalyst's surface acidity on the catalytic activity in the dehydration of methanol to DME. In this work, the conversion of methanol to dimethyl ether has been investigated using a continuous flow fixed-bed reactor at temperatures between 60°C and 350°C and 1 bar. Sulfonated catalysts with –SO3H acid function were tested and compared with conventional catalysts as γ-Al2O3. SiO2, MCM-41 and fluoropolymer were used as inorganic and organic supports for sulfonic groups. The experimental results demonstrate a good catalytic activity for the functionalized MCM-41 and the fluoropolymeric material. Effects of H2O on the activity and deactivation of these catalysts were also studied.

Index Terms—power to gas, methanol dehydration, dimethyl ether (DME), surface acidity, sulfonic supported acids

Cite: Rosanna Viscardi, Vincenzo Barbarossa, Raimondo Maggi, and Francesco Pancrazzi, "Development of Sulfonic Supported Acids and Their Application in Power to Gas Systems," International Journal of Mechanical Engineering and Robotics Research, Vol. 9, No. 9, pp. 1271-1274, September 2020. DOI: 10.18178/ijmerr.9.9.1271-1274

Copyright © 2020 by the authors. This is an open access article distributed under the Creative Commons Attribution License (CC BY-NC-ND 4.0), which permits use, distribution and reproduction in any medium, provided that the article is properly cited, the use is non-commercial and no modifications or adaptations are made.